2013年8月14日星期三

Developments of refractories and corundum, silicon carbide refractories application

Refractories are widely used in metallurgy, building materials, chemicals, nonferrous metals and other high-temperature industrial, which cuts the base material in many fields. Refractories and high temperature industrial interdependence, mutual promotion and common development, China's industrial economic development plays an important supporting role. Of refractory industry has made great progress, in 2010 more than 2,000 enterprises above designated size, yield 28 million tons.
Refractories industry development status of
1 position in the national economy refractories
Refractories are widely used in metallurgy, building materials, chemicals, nonferrous metals and other high-temperature industrial, which cuts the base material in many fields shared. The proportion of high-temperature industrial applications is approximately: 65% steel, building materials, 17%, 4% nonferrous metals, chemicals accounted for 4%, other 10%. Applications involving all sectors of the national economy, the industry and the refractory industry interdependence, mutual promotion and common development, no refractories, there is no high-temperature industrial. Refractory technological advances supporting high-temperature industrial development, the implementation of "energy saving, emission reduction and saving" strategy and "low carbon economy" has played a very important role in promoting.
2 of Refractories Refractories in the international market position
In the iron and steel, nonferrous metals, building materials, chemical industry, electric power and other high-temperature industrial development, driven by the rapid industrial development of refractory materials, production processes, technology, equipment levels rising, continuously improve product quality, variety increasing gradually been recognized by the international market , production and sales has for many years ranked first in the world.
Currently the variety and amount of refractory products not only meet the domestic high-temperature industrial production, development needs, and refractory products export volume increased year by year, the market throughout many countries in Southeast Asia and the Americas, European Union, Russia and other 150 countries (regions). Of refractory industry has been from small to large, from weak to strong, to become the world refractories industry, mainly producing and consuming countries.
As China's industrial structure adjustment and optimization of refractories, asset restructuring, elimination of backward production capacity of the accelerated pace of the strength of some refractory enterprises through the listing and the formation of enterprise groups in the capital and production equipment, has strong technical strength to participate in international competition in the market. The next few years, China will account for a larger refractory international market share, will become a truly world-refractory manufacturing center.
3 of refractories industry development achievements
In recent years, the rapid development of high-temperature industrial technology, driven by strong, China's refractory industry, adhere to scientific development, changing concepts, focus on independent innovation in the optimization and upgrading of industrial structure, product structure adjustment and upgrading of technical equipment as well as in the world refractory industry's competitiveness, etc. have achieved outstanding results for our steel and high-temperature industrial development has laid a solid foundation.
Optimization and upgrading of industrial structure, size and growth. Some refractory enterprises through powerful alliances, mergers and acquisitions, cross-shareholdings and other ways to strategic integration, and promote the refractory industry structure adjustment, optimization and industrial upgrading.
Product structure adjustment, independent innovation ability. In order to meet long-life steel industry blast furnaces to improve converter furnace, refining and efficient continuous casting technology, has developed a special micro-pore structure and the blast furnace process to produce ceramic cup with a slightly corundum brick, Sialon bonded corundum products, blast furnace zone drying strength corundum - nitride - silicon carbide composite castable, non-oxide refractory metal composite oxide containing blast furnace iron runner Si3N4 Si3N4 composite materials and blast furnace gunning, magnesium and calcium brick, tundish ventilation intakes, clean steel casting with carbon-free silicon and thin-slab continuous casting nozzle submerged nozzle and other new products, Baosteel, Anshan Iron and Steel, Wuhan Iron and Steel and other large enterprises to use, and achieved good results. Building materials and other industries for the service, has developed a float glass furnace oxidation no shrinkage casting and regular cast AZS series of cast products, cement kiln directly bonded magnesia chrome brick, magnesia chrome brick semi-combined, the new new dry-process cement kiln tabular alumina castable, National Science and Technology Progress Award of the aluminum reduction cell combined with a silicon nitride nitride brick refractory products, chemicals with a series of high-purity alumina refractory products and other ancillary products in the domestic large-scale enterprises with favorable results, replacing the imported products. Monolithic refractories has been widely applied trough of blast furnace, one pass more than 100,000 tons of iron. Work in the ladle lining life of up to 1000 times. Mixer working lining using all or part of the whole cast replace brick lining, the service life of up to three years. Torpedo using wet jet repair, life expectancy increased by 25% or more. In order to improve construction efficiency and avoiding extreme weather disturbances, ladle castable also adopted a work precast lining. Ladle, ladle, tundish backing by the volume density of 1.6-2.2g/cm3 high strength, low shrinkage semi lightweight castable to reduce heat loss. Large and shaped preform castable used increasingly and exported abroad, such as furnace burners, flue tiles, anchoring brick, brick blast furnace combination, etc., are used castable prefabricated parts. Corundum, silicon carbide materials for the development of these products should play a major role.
Production technology and equipment to accelerate the pace of upgrading. With the rapid development of the refractory industry, refractory production enterprises, key enterprises in particular the level of equipment is constantly upgraded.
4 Refractory Production Status
2010 refractory industry enterprises above designated size was 2,000, yield 28 million tons. Product support, variety, yield higher than the growth rate of fixed assets, the product structure was further optimized to meet the high-temperature industrial and technological progress. Industry on cost control ability level higher equipment levels have significantly improved profitability has been further improved, the industry to promote energy conservation, environmental protection, there is significant progress in the development of refractories industry as a whole more stable.
5 refractory raw resource availability
A wide variety of refractory raw materials, resources are more abundant, which magnesite, bauxite refractory raw materials and other resources called China's pillar, fire clay, silica, dolomite, magnesium olivine, serpentine, zircon and other resources widely distributed, fine texture. These refractory raw material resources for China's refractories industry, providing a reliable foundation conditions.
6 of refractories industry problems
Although our refractories industry has made great progress, but according to the concept and practice the scientific concept of development, the current situation of the development of the industry and the national economy, there are many inappropriate places, the raw material resources, product structure, technology and equipment, consumption levels, energy conservation, environmental protection and industry concentration, there are still some problems with individual products still lags far behind the developed countries.
7 the development trend of refractories
High industry in China will continue to play an important role in the national economy. National development of ten industrial revitalization plan, low carbon development planning and energy saving policies on the development of high-temperature industrial far-reaching significance. Overall control, eliminate backward production capacity, industrial restructuring, technological upgrading and industrial integration is the future direction of development of high-temperature industrial.
Energy saving and recycling economy has become China's high-temperature industrial development of the basic guiding ideology. High-temperature industrial development and direction of the change will be on the development of refractory industry have a significant impact, which will greatly facilitate future sustainable development of stable refractory industry and new technologies, new materials, new technology development and application, which is refractory industry once accelerate technological innovation, the adjustment of product structure rare opportunity for development.
Technological innovation and the development of low-carbon economy will further advance the refractories industry technology innovation, product restructuring and mergers and acquisitions, green, functionality, longevity and other advanced refractory development space and market space increases.
Development of energy efficient refractories, efficient functional refractories, refractory integrated optimization technology systems integration and engineering technology; increase the efficient use of resources and refractory low-grade resource utilization and environmental protection after use eco-refractory refractory material applications; continuously improve the application of refractory technology, give full play to the function of refractories, to achieve consumption and emissions reduction.
Refractory consumption will gradually decline, the total market demand will be maintained at a certain level, the market competition will become more intense. To adapt to the development trend of reduction, refractory enterprises must eliminate backward, the adjustment of product structure, increase the technological upgrading and enhancing service levels to enhance the core competitiveness, but will also increase market integration efforts, improve industrial concentration, and enhance international competitiveness.
Major high industry demand for refractories
Iron and steel industries. The future development of the steel industry: will continue to "control the total elimination of backwardness, mergers and acquisitions, technological innovation, optimize the layout" as the core, control capacity, elimination of backward production capacity, strengthen technological innovation, the development of new materials, iron ore trade norms order to accelerate domestic enterprises to "go out" pace. 2015, construction steel proportion will drop to about 50%, the proportion of steel manufacturing rebound; plates proportion will reach 55%, the key varieties of steel self-sufficiency rate can be increased to about 95%; total production capacity surplus will continue currently half of backward production capacity will be eliminated. Next few years, although the refractory industry will be affected by the presence of iron and steel production by pulling some room for development, but the number used in steel production will continue to decline, it is expected that by 2015, the consumption of refractories will fall 15kg / t steel or so.
Building materials industry. According to China's building materials industry over the past few years the demand for refractories and refractory own development, we can predict the next few years, the building materials industry for refractories demand growth rate will slow down, but the demand will still maintain an upward trend.
The chemical industry. The next few years, the chemical industry will remain above 7% growth, the development of the industry will present different characteristics. According to the World Refractory applications industry statistics, the proportion of the chemical industry use refractory is 4% higher than this level our country. Next few years, the chemical industry will increase total demand for refractories. Large oil refining capacity expansion device and process optimization transformation, will bring some refractory industry development space.
Non-ferrous industries. By 2015, the nonferrous metals industry will further optimize the industrial structure, quality and efficiency improved significantly, significantly enhancing the capability of technological innovation, the main technical and economic indicators have reached the world advanced level, the overall strength jumped to the forefront of the world. Overall, non-ferrous metal smelting industry, the demand for refractories refractory aggregate domestic demand accounted for about 3-5%. Next few years, high-tech, high value-added refractory products demand will increase overall demand for refractory products will continue to maintain about 5%, the growth rate is not too large. Meanwhile, with the non-ferrous metal smelting technology advances and technological progress itself refractory industry, smelting need tons of products also show a downward trend in the amount of refractory material.
Overseas markets. At present, the international refractory products increasingly competitive market, or even to low-disordered unfair competition, export refractory products falling prices. According to statistics, in recent years, ordinary refractory products in the international market prices generally fell by 10%, while the decline of some species can reach 20-30%, as well as by the pressure of RMB appreciation, domestic exports increased the difficulty of refractory products. Refractory products due to the presence of domestic GB market has not yet been fully understood, and some high-end products can not meet the foreign enterprise production technology issues, the next few years, this trend will be maintained within a certain time.
Next few years China refractories overall demand situation. As international and domestic macroeconomic situation for the better, our industry in the next few years will heat usher in a new round of development opportunities, which gives refractories industry has brought opportunities and market space. Can be predicted: the number of refractory market development space is limited, a huge space for adjustment of product structure, service mode conversion will occur, industrial layout adjustment will occur. Refractory aggregate demand will not be much increased, but there will be some increase in high-performance refractory materials, including functional, energy-saving, environment-friendly and other advanced refractories market space will be further expanded, the demand ordinary products decreased.
Basic principles guiding ideology and main objectives
Guiding ideology. To the scientific development as the theme, the main line of independent innovation in order to meet the development needs of high-temperature industrial and international market demand, focusing on promoting industrial restructuring, to create a new model of sustainable development.
Basic principles. Based on domestic resources, and actively explore overseas resources, improve the level of raw material processing equipment, process optimization, rational use of low-grade raw material resources, development of high-grade synthetic refractory raw materials characteristics, the formation of development suited to China's refractory industry, high stability of series refractory raw materials.
Main objective. 2015, achieve significant decline in ordinary products, functional, energy-saving and environment-friendly products such as the proportion of refractory advanced greatly improved to meet the high-temperature industrial and emerging industries for advanced refractory products. Improving product technology content, extend product life and reduce the consumption of refractories, refractory consumption per ton in 2015 to 15 kilograms. Focus on consumption per ton of steel mills close to the international advanced level. Improve industrial concentration, optimize the industrial structure, eliminate backward production capacity to support large enterprises with comparative advantages mergers and acquisitions, foster industrial clusters. By 2015, significantly reduce the number of enterprises to further improve the existing "small, more casual" situation, bred 2-3 home sales reached ,20-30 5-10 billion sales revenue of 10-50 million with strong competitiveness and influence of the refractories business.
Development priorities
The next few years, China's refractory industry is a breakthrough in the development of key industries and key generic technologies, development of new refractory materials, leading the industry development direction. Actively explore special functional refractories, non-oxide composite materials, energy saving refractory materials, environment-friendly refractories, ceramics and other advanced special field of refractories; to China's development of strategic emerging industries, to promote low-carbon economy and high temperature industrial advanced technology as an opportunity , speeding up China's refractories industry, industrial restructuring and industrial upgrading; rational planning, the use of advanced mining and processing technologies, promote the magnesite, bauxite-based refractory materials such as resource utilization development; comprehensively promote the industry energy conservation and clean production; committed to industry standards, and guide the healthy development of industry.
Key development areas
Iron and steel industry new technologies, new processes and major equipment of key development and application of refractories. Steel industry restructuring and technological progress and the acceleration of large-scale equipment in the steel, direct reduction, and other non-coke smelting reduction ironmaking, efficient continuous casting, thin slab casting and other aspects of the refractories industry put forward new requirements and issues . In order to meet the development needs of the steel industry, iron and steel industry to develop refractory to high-performance, long-life, functional refractories and refractory efficient application of technology-based. Focus on research and development of large-scale blast furnace refractories with a long life, clean steel smelting efficient refractories, a new generation of efficient continuous casting refractories function integration, non-refractory coke ironmaking technology key technologies and applications.
Building materials, nonferrous metals, and chemical industries key equipment and key parts of the research and application of refractories. Building materials, nonferrous metals and chemical industry is an important part of our national economy, China's current production of key equipment used in these industries and key parts of the partial refractory Compared with similar products, product quality and performance but also has some gaps , to a certain extent, affected the development of these industries. Focuses on the development of green basic refractories, advanced oxides and fused cast refractories, refractory chrome chrome or low, new non-oxide composite materials, high performance kiln, waste incinerators and ash melting furnace key refractories, foundry porous ceramic filter materials with high technology and applications.
Field of low-carbon energy efficient thermal transfer and the development and application of monolithic refractories. Improve thermal efficiency furnace, reducing energy consumption is to achieve energy saving high temperature industrial focus of development. Research and development of high-temperature insulation refractory material, as well as energy-efficient combustion technology matching, can greatly reduce the energy consumption of industrial furnaces, high temperature industrial energy saving on the whole has a decisive significance. Unshaped refractory materials plays an important role, but also the future direction of development of refractory materials, their production and construction process is simple, can be mechanized construction, environmental protection, high temperature has been widely used in industry. We should vigorously develop, promote the use of a variety of high quality and efficient monolithic refractories, and strive to 2015, the proportion of monolithic refractories around 50%. Focus on research and development of lightweight refractory porous highly fortified industrial technology, super-insulation materials industry prepared nano-technology, high-performance crystal fibers and products of advanced manufacturing technology, high-performance lightweight refractory aggregate production technology, the series monolithic insulating refractory materials, multifunctional monolithic refractories, large and shaped preform preparation techniques, stereotypes of unshaped refractory materials, flame spraying and wet jet technology.
Refractory resource utilization technology development and application. Refractory materials of low resource utilization, waste generated each year iron ore fines, super ten million tons of low-grade ore, a huge amount of revenue and expenditure refractory raw material resources is imperative. Rational use of fine ore, low grade ore is refractory industry limited resources conservation for sustainable development urgent task.
Refractory after use will generate a lot of waste refractories, refractory materials for waste treatment and recycling for environmental protection, clean production and achieving sustainable development of great significance. Focuses on the development and application of low-grade magnesite and bauxite resource utilization of industrial technology, comprehensive utilization of refractory mineral tailings key technologies, high-quality synthetic refractory raw materials, "three stone" (andalusite, sillimanite, kyanite) raw comprehensive and efficient use, recycling and refractory after use and reuse of resource integration technology.
Refractories industry standards and promotion. Existing standards of refractories, refractory industry to promote the development of technology has played an important supporting role. With technological progress, China's refractory industry standard in intellectual property protection, industry development guidance, resource sharing, enterprise participation, standards, international standards, etc., and the reality of our country is not commensurate with the scale of production of refractories, refractory standard system need further improvement to make it more scientific and reasonable. Access standards in the industry, "energy-saving and environment-friendly" standards and refractory products and other new energy standards, the technique should be followed by the development of international standards, to fully absorb the international advanced achievements of refractories, and comprehensively promote to have our intellectual property-based standard system. Focus on the refractories industry access standards (including the energy, environmental protection, scale, variety, etc.) the formulation of new refractory industry testing methods and standards development and promotion of Chinese refractories industry standard internationalization.
Corundum, silicon carbide refractories application
Reform and opening up, high-temperature industrial backward technology and equipment, refractories single species, a large proportion of ordinary refractory materials, corundum, silicon carbide materials rarely, corundum less than 10%, a silicon carbide less than 5%. Technical equipment introduction, digestion, enhance the high-temperature industrial level of technology. High-temperature industrial process equipment technology to improve and enhance the quality of quality refractories made demanding. Corundum, silicon carbide materials resistant to corrosion, slag corrosion, wear resistance, the amount of high-temperature industrial technological progress as needed, with special refractories, unshaped refractories varieties increased the dosage is gradually increased. Such as: iron and steel industry blast furnaces, the iron ditch, Mixer, ladle, continuous casting, electric stove top and other amorphous materials. Such as: cement industry kiln lining material with amorphous silicon Mo bricks. Such as: non-ferrous industrial smelting furnace nitride bonded silicon carbide bricks. Corundum, silicon carbide and other refractory materials to promote the adjustment of product structure.
Market needs, but development is limited. Corundum vigorous market demand, but its supply of raw materials was extremely restricted. Long-term over-exploitation, high alumina refractory clay depleted, if uncontrolled, refractory materials, corundum bauxite resources required, will soon dry up. Since 2010, raising the cost of production factors such as price, make corundum, silicon carbide smelting enterprises have encountered unprecedented difficulties. Currently operating at only 25% of Henan, some companies are forced to move to areas with lower tariffs. Its high cost, high prices, this situation has affected the development of the downstream industry chain.
Future development proposals backward to upgrade equipment. Refractory stable quality performance requirements, need to dump furnace, therefore, in accordance with national policies, the following ordinary corundum phase 3000 kVA and 4000 kVA smelting furnace fixed corundum smelting furnaces. Strictly control capacity expansion, not duplication. Compressed production scale, production efficiency. High alumina refractory clay is already scarce resources, have a plan to protect the refractory materials, corundum use.
High-temperature industrial development is inseparable from refractories, refractory industry's development is inseparable corundum and silicon carbide refractory raw materials!

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